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Low Temperature Anti‑Sulfur Poisoning Catalyst for VOCs Purification

    Low Temperature Anti‑Sulfur Poisoning Catalyst for VOCs Purification

    I. Product Overview: Breakthrough in Sulfur-Containing VOCs AbatementVolatile Organic Compounds (VOCs) emitted from industries such as petrochemicals, coking, and coal chemical processing often contain sulfur-containing impurities (e.g., H₂S, mercaptans, thiophene) at concentrations ranging from 10 to 500ppm. These sulfur compounds easily bind to the active sites of traditional noble metal catalysts, causing irreversible poisoning and rapid activity decay—an industry-wide challenge that limits catalyst service life to 3-6 months in sulfur-containing environments.The Sulfur-Resistant VOCs Noble...
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I. Product Overview: Breakthrough in Sulfur-Containing VOCs Abatement

Volatile Organic Compounds (VOCs) emitted from industries such as petrochemicals, coking, and coal chemical processing often contain sulfur-containing impurities (e.g., H₂S, mercaptans, thiophene) at concentrations ranging from 10 to 500ppm. These sulfur compounds easily bind to the active sites of traditional noble metal catalysts, causing irreversible poisoning and rapid activity decay—an industry-wide challenge that limits catalyst service life to 3-6 months in sulfur-containing environments.
The Sulfur-Resistant VOCs Noble Metal Catalyst addresses this pain point through innovative multi-layer design and material modification. Based on the classic Pt-Pd-Ce system, it integrates rhodium (Rh) as a sulfur-tolerant component and adopts a TiO₂-Al₂O₃ composite support modified by lanthanum (La) and praseodymium (Pr). The unique "sulfur barrier layer + active site protection + sulfur adsorption zone" structure effectively blocks sulfur species from occupying noble metal active sites, while maintaining 95%+ VOC purification efficiency even in gas streams with 100ppm H₂S. Operating at 280-450℃, it achieves synergistic removal of sulfur-containing VOCs and sulfur impurities, eliminating the need for additional desulfurization pretreatment and reducing system investment by 30%+.
The catalyst features a standard honeycomb structure with a grayish-yellow composite coating and 200-300cpi cell density, compatible with modular installation in RCO/RTO systems for sulfur-containing waste gas treatment. Its microstructure consists of 2-5nm noble metal particles uniformly dispersed on the modified support, with La-Pr oxide nanoclusters forming dedicated sulfur capture sites to enhance anti-poisoning performance.

II. Core Technical Parameters Table

Technical Indicators
Detailed Specifications
Remarks
Active Components
Pt, Pd, Rh, Ce, La, Pr
Rh-Pt-Pd ternary system with rare earth modifiers
Noble Metal Loading
0.3-1.2g/L
Higher Rh ratio (15-20% of total noble metals) for sulfur tolerance
Support Material
TiO₂-Al₂O₃ Composite (La-Pr modified)
High sulfur adsorption capacity, 200-300cpi
Appearance Dimensions
Standard 10010050mm/15015050mm, customizable
Compatible with RCO/RTO systems for sulfur-containing gas
Bulk Density
580±50g/L
Ensures stable bed operation in corrosive environments
Operating Temperature Range
280~500℃
Optimal reaction interval: 320-400℃
Maximum Short-term Temperature Resistance
850℃
Resists thermal shock from sulfur oxidation exotherm
Gas Hourly Space Velocity (GHSV)
8000~18000h⁻¹
Adaptable to sulfur-containing gas with variable concentrations
Purification Conversion Rate
>95% (in 100ppm H₂S environment)
Benzene series treatment efficiency: 97%+
Sulfur Tolerance Capacity
≤300ppm (H₂S equivalent)
Maintains activity for 6+ months in 50ppm H₂S
Compressive Strength
≥12MPa
Corrosion-resistant, non-friable
Specific Surface Area
≥250m²/g
Enhances sulfur adsorption and active site exposure
Sulfur Adsorption Capacity
≥5mg/g
Captures sulfur species to protect active sites
Storage Conditions
Sealed, dry environment; avoid sulfur-containing gases
Shelf life: 12 months (unopened)

III. Core Product Features

  1. Superior Sulfur Tolerance: The La-Pr modified TiO₂-Al₂O₃ support forms Lewis acid sites that selectively adsorb sulfur compounds (H₂S, thiophene) through chemical bonding, preventing them from diffusing to noble metal active sites. Rhodium (Rh) forms Rh-S bonds with low stability, which can be oxidized and desorbed during catalyst regeneration, avoiding permanent poisoning. Even in gas streams with 100ppm H₂S, the catalyst maintains ≥95% VOC conversion efficiency for over 6 months, far exceeding the 3-6 month service life of traditional catalysts.

  1. Dual-Function Purification: It achieves simultaneous removal of VOCs and sulfur-containing impurities without additional desulfurization equipment. Sulfur compounds are adsorbed and oxidized to harmless SO₂ (which can be further treated by downstream desulfurization units), while VOCs are converted to CO₂ and H₂O. This dual-function design simplifies the waste gas treatment process, reduces system footprint, and cuts initial investment by 30% compared to "desulfurization + catalytic oxidation" combined systems.

  1. High Catalytic Activity & Stability: The Rh-Pt-Pd ternary active system synergistically enhances catalytic performance—Pt optimizes oxidation of oxygen-containing VOCs, Pd improves activity for aromatics and alkanes, and Rh boosts sulfur tolerance and thermal stability. The La-Pr modified support inhibits sintering of noble metal particles (maintaining particle size at 2-5nm even after 1000 hours of operation) and enhances coating adhesion, ensuring long-term structural stability with compressive strength ≥12MPa.

  1. Wide Adaptability to Working Conditions: It tolerates sulfur concentration fluctuations (10-300ppm H₂S equivalent) and adapts to VOC concentrations ranging from 500 to 10,000mg/m³. The operating temperature range of 280-500℃ accommodates thermal fluctuations in industrial processes, while the GHSV range of 8000-18000h⁻¹ allows flexible adjustment based on gas flow and composition. It also resists poisoning from chlorine-containing impurities (≤50ppm) and high humidity (relative humidity ≤90%), making it suitable for complex industrial environments.

  1. Easy Regeneration & Low Maintenance: When sulfur adsorption reaches saturation (indicated by a 10% drop in purification efficiency or 50℃ rise in light-off temperature), the catalyst can be regenerated by heating to 450-500℃ and purging with air containing 5-10% oxygen for 2-4 hours. This regenerative process can be repeated 3-5 times, extending the overall service life to 2-3 years. Daily maintenance only requires regular inspection of bed pressure drop and purification efficiency, with no need for water washing or chemical treatment.

IV. Core Competitive Advantages

  1. Technological Innovation in Anti-Sulfur Design: The unique "three-layer structure" (sulfur barrier layer, active component layer, sulfur adsorption layer) and Rh-Pt-Pd ternary system address the root cause of sulfur poisoning. Compared to traditional catalysts that simply increase noble metal loading, this design achieves a 5x improvement in sulfur tolerance while reducing noble metal usage by 10-15%, balancing performance and cost.

  1. Total Cost of Ownership Advantage: By eliminating the need for pre-desulfurization equipment (e.g., activated carbon adsorption towers, chemical scrubbers), it reduces initial investment by 30%+. The 2-3 year service life (6x longer than traditional catalysts in sulfur-containing environments) and regenerable design lower replacement and maintenance costs by 40% annually. Low-temperature operation (280-400℃ optimal) further reduces energy consumption by 20% compared to high-temperature anti-sulfur catalysts.

  1. Strong Compatibility with Existing Systems: The standard honeycomb dimensions (10010050mm/15015050mm) and customizable design allow direct replacement of traditional catalysts in existing RCO/RTO units without modifying equipment structure. This enables enterprises to upgrade their waste gas treatment systems with minimal downtime and investment.

  1. Compliance with Strict Environmental Standards: It meets international emission standards (e.g., EU REACH, US EPA) and Chinese national standards (GB 31570-2015, GB 31571-2015), with VOC emission concentrations ≤30mg/m³ and sulfur dioxide emission ≤50mg/m³. It helps enterprises in petrochemical, coking, and other high-pollution industries achieve ultra-low emissions and avoid environmental fines.

V. Application Scenarios

1. Petrochemical & Refining Industry

  • Treatment of sulfur-containing VOCs from crude oil distillation, catalytic cracking, and alkylation processes (e.g., benzene, toluene, xylene, and mercaptans).

  • Application in RCO units for waste gas from storage tanks, loading/unloading operations, and chemical synthesis workshops.

  • Typical sulfur concentration: 50-200ppm H₂S equivalent; VOC concentration: 1000-5000mg/m³.

2. Coal Chemical & Coking Industry

  • Abatement of VOCs and sulfur-containing compounds from coal gasification, coking, and coal tar processing (e.g., phenols, naphthalene, H₂S, thiophene).

  • Suitable for waste gas treatment in coke oven gas purification, methanol synthesis, and ammonia production processes.

  • Typical sulfur concentration: 100-300ppm H₂S equivalent; VOC concentration: 2000-8000mg/m³.

3. Chemical & Pharmaceutical Industry

  • Treatment of sulfur-containing organic waste gas from pesticide, dye, and pharmaceutical synthesis (e.g., thiols, thioethers, and aromatic hydrocarbons).

  • Application in processes involving sulfur-containing raw materials or intermediates, such as mercaptan synthesis and sulfonation reactions.

  • Typical sulfur concentration: 10-100ppm H₂S equivalent; VOC concentration: 500-3000mg/m³.

4. Other Sulfur-Containing VOCs Emitting Industries

  • Leather & Tanning Industry: Treatment of waste gas from leather tanning and finishing (e.g., aldehydes, ketones, and sulfur-containing odorants).

  • Food Processing Industry: Purification of sulfur-containing VOCs from food fermentation and flavoring processes (e.g., hydrogen sulfide from protein decomposition).

  • Waste Incineration Plants: Treatment of sulfur-containing VOCs and dioxins precursors in flue gas (after dust removal and denitrification).

VI. FAQ (Frequently Asked Questions)

  1. Q: What is the maximum sulfur concentration the catalyst can tolerate?

A: The catalyst can stably operate in gas streams with sulfur concentrations up to 300ppm (H₂S equivalent). For concentrations exceeding 300ppm, we recommend installing a simple pre-desulfurization unit (e.g., a small activated carbon tower) to reduce sulfur content to ≤300ppm, ensuring optimal catalyst performance and service life.
  1. Q: How often does the catalyst need regeneration, and what is the regeneration process?

A: Regeneration frequency depends on sulfur concentration: in 50ppm H₂S environment, regeneration is required every 6-8 months; in 200ppm H₂S environment, regeneration is needed every 3-4 months. Regeneration process: ① Heat the catalyst bed to 450-500℃ with clean air; ② Maintain temperature and purge with air containing 5-10% oxygen for 2-4 hours; ③ Cool down to operating temperature and resume use. The process can be completed in the RCO unit without removing the catalyst.
  1. Q: Can the catalyst be used in gas streams containing both sulfur and chlorine impurities?

A: Yes. The catalyst is designed with dual anti-poisoning capabilities: the La-Pr modified support and Rh component resist sulfur poisoning, while the TiO₂-Al₂O₃ composite support inhibits chlorine adsorption. It can tolerate chlorine concentrations up to 50ppm (HCl equivalent) and sulfur concentrations up to 200ppm simultaneously. For gas streams with high chlorine content (>50ppm), contact us for customized chlorine-sulfur dual-resistant catalysts.
  1. Q: What is the difference between this catalyst and traditional anti-sulfur catalysts?

A: Traditional anti-sulfur catalysts typically use high noble metal loading or metal oxides (e.g., V₂O₅) with poor low-temperature activity and short service life. This catalyst adopts a Rh-Pt-Pd ternary system and La-Pr modified support, achieving: ① 5x higher sulfur tolerance; ② 30% lower operating temperature; ③ 2x longer service life; ④ Dual-function purification of VOCs and sulfur compounds. It also avoids secondary pollution from metal oxide catalysts (e.g., V₂O₅ leaching).
  1. Q: How to determine if the catalyst needs replacement instead of regeneration?

A: Replace the catalyst if: ① Regeneration fails to restore purification efficiency (still  2 consecutive regenerations); ② The light-off temperature rises by more than 100℃ compared to the initial value; ③ The catalyst bed shows obvious physical damage (e.g., cracking, peeling); ④ The catalyst has been used for 2-3 years (exceeding the maximum regenerable service life).
  1. Q: What are the key precautions for storage and transportation?

A: ① Store in a sealed, dry environment at 5-35℃, avoiding sulfur-containing gases, moisture, and direct sunlight; ② Transport in packaging with shockproof and moisture-proof protection to prevent collision and damage to the catalyst structure; ③ Use within 12 months of delivery (unopened) to ensure active component stability; ④ Avoid contact with strong acids, alkalis, and organic solvents during storage and installation.


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